SBIR-STTR Award

A Novel Process for the Extraction and Separation of High-Purity Scandium and Rare Earths from Titanium Dioxide Acid Wastes
Award last edited on: 1/24/2023

Sponsored Program
SBIR
Awarding Agency
DOD : DLA
Total Award Amount
$1,100,353
Award Phase
2
Solicitation Topic Code
DLA212-005
Principal Investigator
Athanasios Karamalidis

Company Information

Anactisis LLC

5516 Wilkins Avenue
Pittsburgh, PA 15217
   (412) 346-8016
   info@anactisis.com
   www.anactisis.com
Location: Single
Congr. District: 18
County: Allegheny

Phase I

Contract Number: SP4701-21-P-0097
Start Date: 9/22/2021    Completed: 3/21/2022
Phase I year
2021
Phase I Amount
$100,000
In this project, an advanced simulated moving bed technology will be used to produce selectively and economically efficiently scandium and potential rare earth elements from TiO2 acidic tailings. This technology will utilize proprietary adsorbents as solid phase extractants and eliminate the use of environmentally-unfriendly organic solvents. The adsorbents are capable of selectively adsorbing and separating scandium and rare earth elements from complex acidic solutions. By tuning and optimizing experimental process settings and operating conditions, individually separated, high purity scandium and rare earth salts will be recovered and separated from acidic titanium oxide tailings. In Phase I, the project team will mainly (1) develop a process flow sheet and design a micro-pilot unit, capable of producing at least 2 kg of scandium oxide and additional elements, (2) produce laboratory quantities of at least scandium oxide at 99.9% purity and potentially additional REE salts, and (3) develop cost structures for the proposed technology at commercial scale, including required capital expenditures and per unit production costs. It is anticipated that the production costs of individually separated, high purity scandium and rare earth salts using this technology would be much lower than conventional technologies and processes. The success of this project would shorten the technological gap in the domestic critical elements supply chain. Also, this technology can be commercially applied to separate and recover critical elements from a variety of mining and industrial wastes. It will offer a promising solution to boost domestic critical element production and to create new manufacturing jobs.

Phase II

Contract Number: SP4701-22-C-0086
Start Date: 8/9/2022    Completed: 2/8/2024
Phase II year
2022
Phase II Amount
$1,000,353
The overall objective of Phase II is to develop and prove the concept of producing high-purity scandium and potentially rare earths oxides (or other solids) from titanium dioxide acid waste (TDAW) at a larger scale to a field scale. Specifically, Anactisis will scale up the new separation system developed during Phase I, consisting of a solid-phase extraction (SPE) circuit and a precipitation circuit, for producing primarily scandium (Sc) oxide (or other solid), and secondary other potential critical elements, including a REEmix concentrate or germanium, in a cost-effective and environmentally benign way. The Lead-Lag Column technology will be used in conjunction with Anactisis proprietary selective adsorbent for the separation of target elements from TDAW. The project will validate the concept by constructing and testing a laboratory-scale Lead-Lag Column unit to optimize and troubleshoot the separation of scandium in order to integrate its system to a titanium oxide producer’s facility and to inform the transition to a larger scale system; build and operate intermittently a micro-pilot unit equipped with 2.5L columns; produce scandium oxide quantities for testing with master alloy partners and other potential customers; demonstrate the cost benefits of the proposed technology; prepare engineering designs for larger scale system (1 tpa), and further reduce the risk of technology commercialization through a systems design for process scale-up. The success of this project would shorten the technological gap in the domestic critical elements supply chain. Also, this technology can be commercially applied to separate and recover critical elements from a variety of mining and industrial wastes. It will offer a promising solution to boost domestic critical element production and to create new manufacturing jobs.