SBIR-STTR Award

Advanced Structural Nanomaterials for Astranaut Radiation Protection
Award last edited on: 1/24/2020

Sponsored Program
SBIR
Awarding Agency
NASA : MSFC
Total Award Amount
$669,373
Award Phase
2
Solicitation Topic Code
B1.03
Principal Investigator
Gobinath Balasubramaniyam

Company Information

Zyvex Corporation (AKA: Zyvex Instruments~Zyvex LLC~Zyvex Labs)

1301 North Plano Road
Richardson, TX 75081
   (972) 235-7881
   info@zyvex.com
   www.zyvex.com
Location: Single
Congr. District: 32
County: Dallas

Phase I

Contract Number: ----------
Start Date: ----    Completed: ----
Phase I year
2005
Phase I Amount
$69,776
Polyethylene (PE), due to its high hydrogen content relative to its weight, has been identified by NASA as a promising radiation shielding material against galactic cosmic rays and solar energetic particles. Carbon nanotubes (CNTs), due to their small diameter, high-mechanical strength, and high-electrical and thermal conductivity, are recognized as the ultimate carbon fibers for high performance, multifunctional composites. Prior studies failed to produce the CNT/polymer composites that fully exploit nanotubes' outstanding mechanical, electrical and thermal properties because of poor dispersion of nanotubes in polymer matrices and poor adhesion between nanotubes and the polymer matrix,. Zyvex has developed a versatile and non-damaging chemical platform that allows us to engineer specific nanotube surface properties to permit homogeneous dispersion of nanotubes in various solvents and polymer matrices, and enables the significantly enhanced adhesion between nanotubes and the polymer matrix. The major innovation of our technical approach is to marry these two outstanding materials using Zyvex's chemical platform technology to produce a novel CNT/PE complex composite that not only has high radiation shielding performance, but also has high mechanical strength, high electrical conductivity, and improved thermal stability. Multifunctional CNT/PE complex composite will find broad applications in shielding humans in spacecrafts and habitats.

Phase II

Contract Number: ----------
Start Date: ----    Completed: ----
Phase II year
2006
Phase II Amount
$599,597
Zyvex in cooperation with Prairie View A&M (CARR) and Boeing will develop a space radiation shielding multi-functional material that will provide high energy radiation shielding required to protect astronauts on extended missions, strong enough to be used as an integral structural material and tough enough to survive micro-meteor impacts, provide EMI shielding, and enhanced thermal conductivity. The team will also develop an improved protocol for testing radiation shielding material. This effort will entail developing a composite material which uses proven radiation shielding material Polyethylene(PE), as its primary constituent in the form of very strong/tough Spectra fibers woven into a 3D fabric. In Phase 1 we demonstrated that, compared to bulk PE, this composite approach has significantly improved mechanical properties, excellent electrical conductivity, good Electro Magnetic Interference (EMI) shielding properties, and maintains excellent space radiation shielding properties of PE. We also demonstrated exposure to large doses of high energy actually improved the mechanical properties. In Phase II, the epoxy matrix used in Phase I will be considered along with Cyanate Esters, and Polyimides, As in Phase I, coating the PE fabric and reinforcing the matrix material will be ultra-high strength, highly conductive carbon nanotubes (CNTs). Zyvex's unique and commercially successful CNT processing technology will be adapted to maximize the transfer of the extraordinary mechanical, electrical, and thermal properties of CNTs to the composite structures. The work plan includes approaches to overcome CNT processing and delamination issues discovered in Phase I. CARR will carryout more extensive radiation testing with several ions at different energies. Boeing which has significant interest in developing long term space exploration will guide the development of the material to meet specifications for planned applications.