SBIR-STTR Award

High Porosity Polymer Separators for High Power Lithium-ion Batteries
Award last edited on: 1/24/2007

Sponsored Program
SBIR
Awarding Agency
DOD : MDA
Total Award Amount
$819,914
Award Phase
2
Solicitation Topic Code
MDA03-057
Principal Investigator
John B Olson

Company Information

Boundless Corporation

991 Rainbow Way
Boulder, CO 80303
   (303) 415-9029
   N/A
   www.boundlesscorp.com
Location: Single
Congr. District: 02
County: Boulder

Phase I

Contract Number: ----------
Start Date: ----    Completed: ----
Phase I year
2003
Phase I Amount
$69,937
Boundless Corporation, supported by inventor Kirby Beard, proposes to develop a new micro-porous separator for THAAD, Patriot and other advanced missile technologies requiring high power lithium-based batteries for increased agility, speed and range. Based on a proprietary pore forming material, it promises higher porosity (80% +) with sub-micron pore sizes, excellent mechanical strength and very low production costs. Projected conductivity of up to 8 mS/cm (20oC) could nearly double its power capacity versus Bellcore (4.0 mS/cm) or Celgard technology (est. ~5 mS/cm). Bellcore technology requires costly extraction processing and can leave residual plasticizer, degrading performance. Celgard loses mechanical integrity above 55% porosity, limiting its power capability. Both older technologies are relatively expensive due to complex processing. The new process requires only simple mixing, coating and drying equipment and avoids all post-processing techniques such as extraction, stretching, leaching, etc. often used in producing other separators. Its one-step casting procedure uses low cost solvent systems and will yield estimated cost savings of up to 90% compared to Celgard. It is also amenable to inexpensive plastic substrates like PVC. A potentially broad breakthrough in battery separator technology, it might also enhance performance of aqueous NiCd, lead-acid, and other batteries. Anticipated Benefits/Commercial Applications: Lockheed Martin Missile and Fire Control identifies future generations of THAAD and Patriot missiles and unmanned combat aerial vehicles as key applications for high power lithium batteries, for critical operations such as radar targeting, imaging and jamming. Powerful, periodically testable secondary batteries may replace thermal batteries in many applications. High power commercial batteries are critical to the widespread acceptance of hybrid electric vehicles, and some experts predict all new vehicles will be electric-assist hybrids in ten years. The lithium-ion battery market is projected to reach $3.2 billion by 2007, with an estimated Li-Ion separator market of $160 million. Manufacturers will seek out Boundless' new separator technology to enable higher power from existing electrochemistries and reduce separator costs by as much as 90%. Boundless commercial partners and licensing agreements will help maximize the market penetration of this exciting technology.

Keywords:
battery, separator, structural battery, high power, lithium ion, polymer, multifunctional structure, high specific power

Phase II

Contract Number: ----------
Start Date: ----    Completed: ----
Phase II year
2004
Phase II Amount
$749,977
The porosity of Boundless' new innovative lithium-ion battery separator material is over 45% greater than that of the current state of the art, thereby allowing significantly higher power operation of lithium-ion battery cells. Test cells in Phase I showed increases in power of 28-37% relative to those with Celgardr 2500 separators. The fabrication process for the new separator is significantly simpler than that used for Celgardr and others, and could reduce the cost of the separator for lithium-ion batteries by an estimated 75 to 90%, benefiting both DOD and commercial customers. Boundless demonstrated the simplicity and cost benefits of the new technology by making and testing 147 batches of separator material within the cost and schedule constraints of the Phase I contract. Phase I research yielded an understanding of the parameters affecting separator porosity and strength used to optimize performance, and culminated in the demonstration of lower-resistance lithium-ion battery cells incorporating the new separator. Commercial collaborators will support Boundless in the Phase II effort. A coatings manufacturer will help develop pilot production processes and optimize the separator in the context of a production environment, and a commercial battery manufacturer will incorporate and test the new separator in commercial cells.