SBIR-STTR Award

Affordable Ultracapacitors Based on Carbon Nanofibril Electrodes
Award last edited on: 11/27/02

Sponsored Program
SBIR
Awarding Agency
DOD : MDA
Total Award Amount
$759,998
Award Phase
2
Solicitation Topic Code
BMDO96-005
Principal Investigator
Chung Ming Niu

Company Information

Hyperion Catalysts International

38 Smith Place
Cambridge, MA 02138
   (617) 354-9678
   info@hyperioncatalysis.com
   www.nanotubes.com
Location: Single
Congr. District: 05
County: Middlesex

Phase I

Contract Number: DASG60-96-C-0129
Start Date: 4/29/96    Completed: 10/29/96
Phase I year
1996
Phase I Amount
$60,000
Electrochemical capacitors, sometimes called ultracapacitors, or supercapacitors, are of interest for hybrid electric vehicles and other automotive electronic and military systems. To be cost and weight effective compared to batteries, they must combine adequate specific energy and specific power with long cycle life, and meet cost targets as well. Hyperion's commercial nanotube product, Graphite Fibrils', with a high available surface area of 200 sq.m/gm, has been initially measured to have a capacitance of 86 F/gm. This contains a substantial Faradaic contribution. It is proposed in Phase I to enhance Faradaic contributions via post treatment of the nanotubes. Phase II will use the Phase I results to design, fabricate and test electrochemical capacitors.

Phase II

Contract Number: DASG60-97-C-0049
Start Date: 6/10/97    Completed: 5/31/99
Phase II year
1997
Phase II Amount
$699,998
In May 1996, Hyperion Catalysis International, Inc. began work under a Phase I SBIR contract aimed at affordable high performance electrochemical capacitors based on our proprietary carbon nanofibers. Phase I has already demonstrated that very high power density can be achieved. Further, the electrodes have excellent frequency response characteristics, also important for pulse power uses. Finally, the form of the electrodes, robust semi-rigid mats, appears to be of great interest to the capacitor community because it may reduce fabrication costs. The goal of Phase II is to demonstrate performance of a practical carbon nanofiber electrochemical capacitor, consistent with the Phase I results to date, i.e. power density on a cell basis of ca. 8.0 KW/Kg and energy density on a cell basis in excess of 2.5 KJ/Kg. Acceptable cycle life, leakage current and cost will also be demonstrated. By a practical capacitor, we mean one produced by a capacitor manufacturer from electrodes supplied by Hyperion. The electrodes, in turn, would be made from our commercially available nanofibers by a scaleable pilot line using chemical treatments, to alter the surface functional groups, and both chemical and physical methods to affect the texture of the electrodes.