SBIR-STTR Award

Additive manufacturing to enable high performance salt-hydrate based thermal energy storage products
Award last edited on: 12/30/2020

Sponsored Program
STTR
Awarding Agency
DOE
Total Award Amount
$1,298,437
Award Phase
2
Solicitation Topic Code
16a
Principal Investigator
Wale Odukomaiya

Company Information

TCPoly Inc

878 Peachtree Street Ne Unit 414
Atlanta, GA 30312
   (336) 391-9634
   N/A
   www.tcpoly.com

Research Institution

National Renewable Energy Laboratory

Phase I

Contract Number: DE-SC0020764
Start Date: 6/29/2020    Completed: 4/28/2021
Phase I year
2020
Phase I Amount
$199,987
Building energy consumption for heating and cooling accounts for a large portion of energy usage and CO2 emissions in our country. Thermal energy storage (TES) materials (such as phase change materials (PCMs)) have the potential to increase a building’s thermal mass and provide flexibility to time?shift demand. Hence, PCMs can be used to reduce demand changes, take advantage of time?of-use rates, better match distributed generation output, or improve efficiency of the building and the grid. Despite these potential advantages, PCMs have not been widely adopted due to high cost, susceptibility to combustion, low heat transfer properties and relatively low volumetric energy density. Through collaboration with the National Renewable Energy Laboratory (NREL), TCPoly, Inc. will utilize 3D printing to create low-cost, durable, and high-energy-density structures for thermal energy storage in buildings. The technology is based on microencapsulated inorganic salt hydrate PCMs that are encapsulated in thermally conductive polymers (TCPs) and maintain encapsulation through the 3D printing process. 3D printing enables large-scale 3D printed objects that maintain domain control of PCM and TCP compositions on the micron scale, thus improving the performance of salt hydrate PCMs (reduced supercooling, increased thermal conductivity and cycle lifetime). Moreover, by enabling the use of low-cost filament-fed fused deposition modeling (FDM) 3D printers, complex phase change heat exchanger geometries can be fabricated to enhance and control charge and discharge rates. This proposal will result in the first commercially available high-performance TES material that can be manufactured through the simple and relatively low-cost FDM 3D printing method. Therefore, the proposed material will serve as a platform technology that can be used for both thermal energy storage and thermal management applications across a multitude of industries.

Phase II

Contract Number: DE-SC0020764
Start Date: 8/23/2021    Completed: 8/22/2023
Phase II year
2021
Phase II Amount
$1,098,450
Phase change materials (PCMs) store large amounts of latent heat during phase transitions and, therefore, are used as thermal energy storage (TES) materials in a variety of applications. Applications of TES in buildings are of particular interest for their potential to increase a building’s thermal mass and provide flexibility to time?shift demand for grid-interactive efficient buildings (GEBs). Moreover, PCMs can be used to reduce cooling loads in datacenters/telecom applications and to improve the efficiency of clean energy technologies such as electric batteries. Salt hydrates are one of the most promising PCM materials with high energy density and lower cost, but are prone to significant subcooling effects, phase segregation, cycling hysteresis, and corrosiveness. TCPoly will collaborate with NREL and PCS to 3D print PCM products integrated with TCPoly’s thermally conductive polymers. Leveraging thermally conductive polymers and additive manufacturing to fabricate TES products provides an opportunity to overcome Salt-hydrate PCM limitations while also enabling unmatched control over geometry. Therefore, our solution allows for optimization of PCM/thermally conductive matrix structure and heat exchanger geometry for controlled charge and discharge characteristics, high efficiency, and reduced system costs.