SBIR-STTR Award

Oil Deoxygenation for Higher Temperature Stability
Award last edited on: 11/11/2009

Sponsored Program
SBIR
Awarding Agency
DOD : AF
Total Award Amount
$747,522
Award Phase
2
Solicitation Topic Code
AF083-106
Principal Investigator
Stephen Walker

Company Information

Phyre Technologies Inc

1950 Cordell Court Suite 104
El Cajon, CA 92020
   (619) 448-0904
   info-gobiggs@phyre.net
   www.phyre.net
Location: Single
Congr. District: 53
County: San Diego

Phase I

Contract Number: ----------
Start Date: ----    Completed: ----
Phase I year
2009
Phase I Amount
$99,796
In order to increase efficiency, modern propulsion systems are required to operate at significantly higher temperatures than in the past.  An increased heat load is therefore placed on the fuel that is used as a coolant and on the engine lubrication system.  Lubricating oils are typically limited to working temperatures below about 400F.  Oil deoxygenation presents an attractive option for significantly increasing this temperature limit. We propose to develop a novel system that will be capable of deoxygenating inline the complete lubricating oil flow for a typical modern military aircraft.  The proposed system will use a fixed volume of recycled, essentially oxygen free nitrogen gas to remove the dissolved oxygen from the oil within a contacting device.  The oxygen will then be eliminated chemically from the nitrogen in a catalytic converter so that the gas may be returned to the contactor for repeated oxygen stripping. We will perform tests on various contacting devices and a catalytic converter to demonstrate and characterize the deoxygenation characteristics of MIL spec lubricating oil.  We will use these data to make projections of the size, weight and durability for a full-scale deoxygenation system and the dependence of this projection upon the output dissolved oxygen level.

Benefit:
Lubricating oil may begin to loose its effectiveness as its temperature is raised to around 400F and oxidation begins to occur.  Oil must therefore be maintained below this critical temperature.  This imposes a limit on engine operating windows and may require large, heavy heat exchangers to cool the oil.  By removing the dissolved oxygen from the lubricating oil it is anticipated that its maximum operating temperature may be substantially increased.  This will be beneficial to both the engine designer and operator as follows: 1) The designer may save weight, as the lubricating oil will require a smaller, lighter heat exchanger to transfer heat away to the air or fuel cooling fluid. 2) The designer may increase engine peak cycle temperatures since the oil within the lubrication system can sustain a greater temperature before breakdown occurs. 3) The end user may reduce maintenance cycle frequency as the oil will tend to deteriorate at a decreased rate Both military and civilian designers and end users of both gas turbine and reciprocating power plants may realize these benefits.  For the civilian and military aircraft markets, the reduced weight and increased engine temperatures will make oil deoxygenation a very appealing option for increasing aircraft cycle efficiency and power-weight ratios.  For larger, ground based and ocean going power systems, size and weight may not be such a concern.  However, deoxygenation will inevitably present significant potential savings of maintenance costs arising from reduced system down time, labor costs and oil usage. BENEFITS OVER OTHER TECHNOLOGIES We are not aware of other commercial or experimental technologies being developed for deoxygenation of lubricating oil.   Efforts have been made to perform online deoxygenation of jet fuel using membrane technology.  However, membranes are typically large, heavy, fragile and prone to fouling.  They also require a continuous high flow rate of oxygen free gas that must be supplied from engine compressor bleed.  This requires a gas-gas heat exchanger and additional mechanical components.  We have conducted experiments concerning the deoxygenation of jet fuel using a fuel-gas contactor system.  However the device used for that work is unsuitable for much thicker lubricating oil.  

Keywords:
Oil, De-Oxygenation, Thermal Stability, Lube Oil, Catalyst, Gas Turbine

Phase II

Contract Number: ----------
Start Date: ----    Completed: ----
Phase II year
2010
Phase II Amount
$647,726
The maximum temperature at which turbine lubricating oils may operate is limited by the process of chemical oxidation, which occurs at temperatures between about 350-400F. One technique that may be used to delay the onset of oxidative breakdown is to deoxygenate the oil before heating occurs. In Phase I we proposed and tested the key components of PODS, Phyre’s Oil Deoxygenation System, that is capable of performing online deoxygenation of turbine oils. This system is capable of reducing the dissolved oxygen content of oils in real time to of order 0.1% of the saturated value, or about .03ppm. In Phase II we will continue development of PODS. We will perform characterization experiments at higher temperatures to determine the benefits of higher temperature operation. We will investigate the possible impact of the small amount of water produced within the catalyst on the lubricating system. Mitigation will be proposed if necessary. In a collaborative effort with a leading aero engine manufacturer, we will investigate the rate of oil re-oxygenation in laboratory testing using a realistic model of a turbine bearing. A complete PODS will be built that is capable of performing oil deoxygenation and laboratory tests will be carried out at UDRI.

Benefit:
advanced thermal management systems for turbine engines

Keywords:
Turbine Oil, Deoxygenation, Lube Oil, Thermal Management