SBIR-STTR Award

A dechlorination system for megnetohydrodyanamic spent seed
Award last edited on: 4/10/02

Sponsored Program
SBIR
Awarding Agency
DOE
Total Award Amount
$550,000
Award Phase
2
Solicitation Topic Code
-----

Principal Investigator
William D Jackson

Company Information

HMJ Corporation

10400 Connecticut Avenue Suite 404
Kensington, MD 20895
   (301) 946-1586
   N/A
   N/A
Location: Single
Congr. District: 08
County: Montgomery

Phase I

Contract Number: ----------
Start Date: 00/00/00    Completed: 00/00/00
Phase I year
1992
Phase I Amount
$50,000
In coal-fired open-cycle magnetohydrodynamic (MHD)powerplants, a key issue is chloride buildup. A furtherconsideration is that under the 1990 Clean Air Act amendments,emission of hydrochloric acid (HCI) gas/aerosol from a continuoussource must be brought below 10 tons/year. Potassium added in theMHD system upstream, to create plasma conductivity and achievesulfur dioxide removal, can also control HCI emission if added insufficient quantities. However, the resulting chlorides from thespent seed materials must be removed or their concentrations mustbe reduced to control their buildup in the recycled seed. Todechlorinate the spent seed material without losing a significantquantity of potassium, the University of Tennessee Space Institute(LTTSI) has developed an ionexchange resin-based concept. Thisconcept is simple, uses mild operating conditions, is based onexisting technology of water softening, and offers a potentiallyattractive option to simultaneously carry out dechlorination anddesulfurization of the MHD spent seed at an overall costsignificantly lower than the option currently being developed. Incooperation with UTSI, commercially available candidate resins arebeing screened in Phase I to select one or two for furtherdevelopment in the Phase II period. The necessary process flowsheets are also being developed to integrate seedrecovery/regeneration operations with the proposed dechlorinationsystem for integrated MHD plant. In Phase II of the project, anintegrated demonstration will be undertaken using UTSI facilities; the resulting dechlorinated and desulfurized materials would berecycled to an MHD combustor.Anticipated Results/Potential Commercial Applications as described by the awardee:The successful completion of the project willprovide a technically attractive option to simultaneouslydechlorinate and desulfurize the MHD spent seed material at anoverall cost considerably lower than could be expected for theapproach currently being developed. It could resolve a criticaltechnical issue and greatly improve the prospects for acceptance ofMHD technology by the electric industry and its suppliers.

Phase II

Contract Number: ----------
Start Date: 00/00/00    Completed: 00/00/00
Phase II year
1993
Phase II Amount
$500,000
The open cycle magnetohydrodynamic (MHD) coal-fired powerplants have the potential to provide substantial improvements inthe thermal efficiency of electric power generation, but severalkey engineering issues must be resolved before these improvementscan be achieved. One of these is efficient processing of theseed added to the combustion products to render them electricallyconducting. This seed has to be reprocessed and, in the process,the conditions exist for chloride buildup, The chloridesresulting from the spent seed material must be removed, or theirconcentration reduced, to control their buildup in the recycledseed. Further, the system in which this is done must be capableof integration into the MHD/steam combined cycle without adverseeffect on its performance. To dechlorinate the spent seedwithout losing potassium, the University of Tennessee SpaceInstitute (UTSI) has developed an anion exchange resin-basedconcept. This concept is simple, uses mild operating conditions,and is based on existing technology of water softening. Itoffers a potentially attractive method to carry outsimultaneously the desulphurization and the dechlorination of MHDspent seed at an overall cost significantly lower than theprocess currently being developed. Phase I resulted in theselection of two suitable resins and a preliminary demonstrationof the feasibility of the process. In Phase 11, system analysiswill be conducted to identify the preferred operating conditionsof the seed reprocessing system, a process demonstration unitwill be built and operated on the Coal-Fired Flow Facility, andengineering data on its operation will be obtained. These datawill be used to undertake the conceptual design of an MHD plantincorporating the UTSI process. The process is particularly suited to high sulphur coal. Tofacilitate comparison with conceptual designs, the Scholz Planthas been selected to provide the MHD/steam interface for the integrated conceptual design. The project will includethe development of a data base designed for prototype andcommercial scale plants.Anticipated Results/Potential Commercial Applications as described by the awardee:Successful completion of the projectwill provide a technically attractive option to simultaneouslydechlorinate and desulfurize the MHD spent seed material at anoverall cost considerably lower than what can be expected for theapproach currently under development. It will resolve a criticaltechnical issue and greatly improve the prospects for acceptanceof MHD technology by the electric industry and its suppliers.