SBIR-STTR Award

Solar fuels generators harness solar energy as the power source to facilitate the generation of either hydrogen or carbon based fuels. In both cases, water is electrochemically oxidized to produce oxygen, protons and electrons at the anode. Hydrogen or carbon based fuels are produced simultaneously at the cathode by the reduction of protons or carbon dioxide, respectively. Ion exchange membranes are a critical component of the system, but membranes currently available were developed for other applications and do not meet the specific requirements of this developing technology. This work will focus on the development of new proton exchange membranes that address the challenges of both solar-to-hydrogen and solar-to-carbon fuels generators. Specific requirements to be addressed include reduced hydrogen permeation (to improve efficiency and limit hazardous mixing of hydrogen and oxygen), reduced costs and improved durability compared with current commercially available materials. Additional requirements for solar-to-carbon fuels membranes include chemical stability and low permeability to complex mixtures of potential products such as methane, methanol, ethanol and ethylene. Our Phase I approach will be to initially obtain baseline data for the performance of our existing ion exchange membrane technology in this new application. The backbone molecular architecture and chemical functionality of our unique polymers will then be systematically modified and membranes reassessed in order to highlight the most promising pathways to meet critical performance requirements. Membranes will be tested for conductivity, permeability (to hydrogen and key carbon dioxide reduction products) and durability at state of art facilities. Success of this work would be an important step towards realizing the goal of achieving cost effective renewable fuel production. Examples of three critical areas which would be affected by success in the proposed work include industrial gas applications/chemical feedstocks, transportation fuels and power backup/storage. For each of these applications, the use of solar generated fuels would result in a reduced dependence on fossil fuels and the associated economic, political and environmental issues related to their extraction, refinement, supply and final use.

Solar fuels generators harness solar energy as the power source to generate either hydrogen or carbon-based fuels. In both cases, water is electrochemically oxidized to produce oxygen, protons and electrons at the anode. Hydrogen or carbon-based fuels are produced at the cathode by the reduction of protons or carbon dioxide, respectively. Ion exchange membranes are a critical component of the system, but current commercially available membranes do not meet the challenging requirements of this developing technology. This work will focus on the development of new cation exchange membranes that address the challenges of both solar-to-hydrogen and solar-to-carbon fuels generators. Novel membranes will be developed which demonstrate reduced hydrogen permeation (to improve efficiency and limit hazardous mixing of hydrogen and oxygen), reduced costs and improved durability compared with existing materials. Additional requirements for solar-to-carbon fuels membranes such as chemical stability and low permeability to complex mixtures of potential products such as methanol are also being addressed. During Phase I we successfully demonstrated the fabrication of novel membranes which outperform current commercial materials in many of the key requirements for effective solar fuels membranes. This was achieved through systematic modification of the molecular architecture and chemical functionality of an ion exchange membrane technology previously developed in our laboratories for other applications. As a result of this work we have down-selected two of our best performing materials which demonstrate good conductivity in conjunction with significantly improved hydrogen and methanol permeability characteristics compared with current commercially available membranes. During Phase II, we plan to further optimize and develop our Phase I down-selected materials. Our primary focus will be toward optimizing performance and evaluating and understanding possible failure mechanisms and developing methods to ensure long term stability and durability under solar fuels generator operating conditions. Techniques demonstrated during Phase I to enhance stability and reduce permeability to carbon dioxide reduction products will be further developed. Success of this work would be an important step towards realizing the goal of achieving cost effective renewable fuel production. Examples of three critical areas which would be affected by success in the proposed work include industrial gas applications/chemical feedstocks, transportation fuels and power backup/storage. For each of these applications, the use of solar generated fuels would result in a reduced dependence on fossil fuels and the associated economic, political and environmental issues related to their extraction, refinement, supply and final use.